I'm having a bit of trouble understanding precisely what you mean, but I shall attempt to answer your questions.
All examples below are using Audacity 1.3.4.
"Export Selection" and "Export Multiple" are different.
"Export Multiple" enables you to split a recording at a number of places in time and produce a separate audio file for each part. This is typically used if you record an LP or a tape and you want each "song" top be a separate audio file.
There is a brief explanation of this here:
http://audacityteam.org/help/faq?s=files&i=split
There is a more detailed explanation here:
http://audacityteam.org/wiki/index.php? ... ate_tracks
"Export Selection" enables you to export the selected region of one or more tracks as one single audio file.
Examples of "Export Selection":
Example 1.
You have a project with 4 tracks and you want to export each track individually.
Example: track 1 becomes
file-one.wav, track 2 becomes file-two.wav, track 3 ->
file-three.wav, track 4 ->
file-four.wav
To do this, select track 1, then choose "Export Selection" from the file menu. Follow the on-screen dialogue, select the file format, destination folder etc.
Repeat the procedure for each of the tracks.
Note: (and this is where the problems can occur)
"Export Selection" will only export audio that exists.
Audacity 1.3.x allows you to place audio clips anywhere on the time line, but "Export Selection" will not export empty space at the beginning or end of an audio clip.
"Silence" is counted as valid audio data, but an empty space is not.
Example 2.
Let us say that you have an audio clip that starts at time=5 seconds and ends at time=10 seconds.
You then try to select and export that track from time=0 to time=30 seconds.
This will not create 5 seconds of silence at the beginning of the exported audio, or 20 seconds of silence at the end because there is no audio data there to export.
The exported audio will only include the region from the start of the audio clip to the end of the clip. In other words, a 5 second clip.
There is one exception to this, and that is if you have two or more clips with gaps between them, and your selection includes two or more of these clips.
Example 3.
In the image below you can see an example.
Track 1 is our original track and I selected from time=1 second to time=3 seconds, then exported the selection.
Track 2 is the exported file after it has been imported back into Audacity.
Note that the gaps between clips has been replaced with silence and our exported audio file is 2.0 seconds long.
The gap between the end of the third audio clip (at about time=2.8 seconds) and the end of our selection (time=3.0 seconds) has also been replaced with silence. This is because Audacity is aware that there is still more audio on track 1 yet to come (the 4th and final clip on track 1).

- Screenshot-1.png (11.31 KiB) Viewed 3397 times
Example 4.
If in Example 3 we want to be able to import the clips back into Audacity (or some other program), and want the clips to line up correctly in the time line, then clearly we need our selection to start at time=0
BUT we have a gap at the beginning of our track, and this gap will NOT be included in out exported audio.
The solution to this is to turn our track (render) into a continuous audio track that starts at time=0.
To do this, we select the track, then from the "Tracks" menu click on "Mix and Render".
The result is as in this image:

- Screenshot-2.png (8.08 KiB) Viewed 3397 times
If we compare this to the previous image we can see that the gaps have been "filled in" with silence, so now we can export this track, and it will start at time=0
Tips:
The following "hot keys" can make the above process quicker - particularly useful if you have lots of tracks:
[Enter] = select/deselect current track
[Home] = move to start
[End] = move to end
[Shift]+[Home] = select from cursor position to the start
[Shift]+[End] = select from cursor position to the end
Down cursor = next track down
Up cursor = next track up
[Alt]+T then M = Mix and render (selected tracks)
[Alt]+F then R = Export selection
Putting these together -
Up/Down cursor keys to the track that we want to export, then
[Enter] - (select track)
[Home]
[Shift]+[End] - (selected track is now highlighted)
[Alt]+T then M - (track is now rendered)
[Alt]+F then R - (Export selected)
Regarding Exporting audio that is before time=0
Using the normal "Export" command from the file menu will Export a mix of all tracks, starting at time=0 to the end.
Using "Export Selection"
can export audio that exists
before time=0
provided that it is selected.