I've just discovered that all of my supposed 32-bit 96KHz recordings are only in 16 bit.
The problem was that although the recording quality is clearly displayed on the track, the exported file quality is not. Normally I'd expect there to be a preferences global settings page containing the bit depth options that I'd configure up-front, but this seems to be rather buried under the Options button on the per-export File Save dialogue box.
Also originally I'd started exporting in wav format, not realising that it was only 16 bit wav (I thought the 16 bit signed was referring to something else) and then progressed to flac (but this defaults to 16 bit). And I've only just found:
1) the prefs page has a note saying that the quality options are on the export dialogue options button,
2) >16 bit wav is only available by selecting "other uncompressed files" - I'd never thought of looking there
It's too late for me to go back and re-rip hundreds of discs so hopefully this sorry tale will help prevent someone else hitting this.
Or maybe the quality options can be made more visible (or even a warning indicating that you are exporting in a lower quality than the recording).